Origin of sulphate in the unsaturated zone and groundwater of a loess aquifer     

Yin Long  Tianming Huang  Fen Zhang  Zhenbin Li  Baoqiang Ma  Yiman Li  Zhonghe Pang 《水文研究》2021,35(4):e14166

The use of the sulphate mass balance (SMB) between precipitation and soil water as a supplementary method to estimate the diffuse recharge rate assumes that the sulphate in soil water originated entirely from atmospheric deposition; however, the origin of sulphate in soil and groundwater is often unclear, especially in loess aquifers. This study analysed the sulphur (δ³⁴S-SO₄) and oxygen (δ¹⁸O-SO₄) isotopes of sulphate in precipitation, water-extractable soil water, and shallow groundwater samples and used these data along with hydrochemical data to determine the sources of sulphate in the thick unsaturated zone and groundwater of a loess aquifer. The results suggest that sulphate in groundwater mainly originated from old precipitation. When precipitation percolates through the unsaturated zone to recharge groundwater, sulphates were rarely dissolved due to the formation of CaCO₃ film on the surface of sulphate minerals. The water-extractable sulphate in the deep unsaturated zone (>10 m) was mainly derived from the dissolution of evaporite minerals and there was no oxidation of sulphide minerals during the extraction of soil water by elutriating soil samples with deionized water. The water-extractable concentration of SO₄ was not representative of the actual SO₄ concentration in mobile soil water. Therefore, the recharge rate cannot be estimated by the SMB method using the water-extractable concentration of SO₄ in the loess areas. This study is important for identifying sulphate sources and clarifying the proper method for estimating the recharge rate in loess aquifers.  相似文献   

甘肃北山老金厂金矿床载金矿物特征、原位硫同位素组成及其对成矿的指示意义     

黄式庭  于晓飞  吕志成  刘家军  李永胜  杜泽忠  吕鑫  孙海瑞  杜轶伦 《吉林大学学报(地球科学版)》2020,50(5):1387-1403

老金厂金矿床是北山成矿南带最具代表性的中低温岩浆热液型金矿床之一，其规模为中型。依据脉体穿插、矿物共生组合和矿石结构构造等特征，将矿床矿化作用过程划分为石英-黄铁矿阶段（Ⅰ）、石英-含砷黄铁矿-毒砂阶段（Ⅱ）、石英-黄铁矿-多金属硫化物阶段（Ⅲ）和石英-方解石阶段（Ⅳ）。利用电子探针研究了不同成矿阶段载金矿物的元素组成及其分布规律。Ⅰ阶段：黄铁矿以粗粒自形立方体为主，粒度为0.50~1.50 mm，贫As、Au；毒砂含量极少，呈细粒他形。Ⅱ阶段：含砷黄铁矿周围常有大量毒砂产出，含砷黄铁矿多为立方体、五角十二面体，粒度为0.30~1.00 mm，富As、Au；该阶段矿化最为强烈，毒砂主要形成于此时期，多呈棱柱状、柱状、放射状集合体，显示富S亏As特征。Ⅲ阶段：多以黄铁矿-黄铜矿-闪锌矿共生组合脉的形式产出，黄铁矿多呈长条状，以富S、Cu、Zn、Au和贫Fe、As为特征。Ⅳ阶段：矿化作用极弱，毒砂、黄铁矿含量极少，为细粒他形。原位硫同位素组成显示：Ⅰ阶段黄铁矿δ³⁴S_V-CDT值为-3.8‰~-2.9‰，均值为-3.3‰；Ⅱ阶段黄铁矿和毒砂δ³⁴S_V-CDT值为-4.7‰~2.6‰，均值为-3.3‰；Ⅲ阶段黄铁矿和闪锌矿δ³⁴S_V-CDT值主要分布于-1.9‰~1.0‰之间，均值为0.1‰。此3个阶段硫同位素组成反映了成矿期硫主要来源于幔源岩浆，混入了部分地层硫。综合前人研究成果，认为成矿早期至晚期，成矿流体总体上由富S贫As向富As贫S演化。Ⅰ阶段体系处于中性稳定的环境，硫源充足；Ⅱ阶段为贫S富As的高氧逸度环境，由于大气降水对地层的淋滤渗透，混入富As流体，Au可能与As结合形成Au-As络合物，在成矿有利部位富集沉淀；Ⅲ阶段成矿元素种类丰富，体系为富S贫As的弱还原环境，Au很可能与HS^-、S^-形成络合物进入黄铁矿晶格。  相似文献   

东昆仑金水口地区格林威尔期超高温麻粒岩   总被引：1，自引：1，他引：0  

何凡  宋述光 《岩石学报》2020,36(4):1030-1040

格林威尔期构造事件是了解罗迪尼亚超大陆形成的关键。本文报道了东昆仑造山带东段金水口地区古生代花岗岩中新发现二辉麻粒岩包体,其峰期变质矿物组合为单斜辉石+紫苏辉石+钙长石+石英+磁铁矿。通过锆石U-Pb测年,我们确定二辉麻粒岩样品的峰期变质年龄为995±34Ma,并受到泥盆纪(～417Ma)构造热事件的叠加改造。利用单斜辉石-斜方辉石温压计估算出该区二辉麻粒岩变质峰期温度867～1079℃,压力46～89kbar,属于低压超高温变质的温压范围,可能形成于高地温梯度的岛弧环境。该二辉麻粒岩是首次在东昆仑地区发现的格林威尔期超高温麻粒岩,代表罗迪尼亚超大陆汇聚过程中低压高温变质的产物。该发现对了解东昆仑造山带前寒武纪基底的构造属性和起源有重要意义。  相似文献   

天然裂缝影响下的花岗岩水力裂缝扩展数值模拟     

王璜  王贵玲  岳高凡  甘浩男 《地质学报》2020,94(7):2124-2130

水力压裂技术是成功实现干热岩资源开发利用的重要手段之一，数值模拟技术能够精准预测水力裂缝扩展。针对典型花岗岩，借助黏性单元法，分别模拟了致密花岗岩和天然裂缝存在情况下的水力裂缝扩展特征，得出以下结论：致密花岗岩的水力裂缝形态单一，天然裂缝的存在增加了压裂后裂缝的复杂性；致密花岗岩水力裂缝拓展主要分为憋压和拓展两个交替往复的阶段，当存在天然裂隙时，水力压裂过程会变得复杂；天然裂缝存在时，水力裂缝的缝长和缝宽分别为致密花岗岩的5. 7倍和1. 7倍；缝网的形成需要借助复杂的压裂工艺实现。研究结果可以为增强型地热系统(EGS)储层水力刺激工作提供理论支持。  相似文献   

湍流度随高度的变化及其对城市宏观地形的依赖     

李大全  孙武  欧阳睿康  黄盛  高梦媛  李庆祥  黄启明 《热带地理》2019,39(3):365-376

分别构建广州主建成区垂直比例尺为1﹕2 000、1﹕1 000和1﹕500的3个建筑物模型，利用大型边界层风洞，在西北和东南两风向下，基于中性流模拟分析了复杂城市地形下湍流度随高度的变化及其对宏观地形的依赖。结果表明：风廓线指数α与不同高度的湍流度之间的关系密切，利用现有模型，根据4类粗糙度边界层和不同垂直比例尺，可确定相应的湍流度随高度变化模型的主要系数，预测精度高。城市地形下最大湍流度面发育在0~0.2 h之间狭窄的范围内。用湍流度形态指数β来表征湍流度随高度的变化，无论城市屋脊还是平坦地形，随着风程区的延伸，廓线的指数α升高，湍流度形态指数β降低。表明同一高度湍流度值具有由迎风区、丘顶区向背风区增高，沿风程逐渐增大的规律，对地形部位和风程的依赖性强，与来流翻越简单地形时的特征一致。  相似文献   

The Control of the Spatial and Temporal Differential Evolution of Boundary Faults on Faulted Basins     

Yuhu Liu  Chunhui Cao  Ruilei Li  Jianfeng Zhu  Wen Xu  Lan Huang  Ying Luan 《地球科学进展》2020,35(1):79-87

The boundary faults of faulted basins generally have segmental growth characteristics. Quantitative analysis of fault growth processes and combined models is of great significance for basin formation and evolution and hydrocarbon accumulation. Taking the Fulongquan fault depression in the southern part of the Songliao Basin as an example, using the 3D seismic data and using the fault-displacement length analysis method, the segmental growth and evolution process of the boundary fault is systematically studied, and the control effect of the spatial and temporal differential evolution of boundary faults on faulted basins is analyzed. The study shows that the segmental growth control of the boundary fault of Fulongquan fault depression forms a series of semi-mantle shoals; the sedimentary center of the Shahezi-Yingcheng fault is controlled to migrate from south to north; The slanting and thrusting activities control the height of the anticline trap; the transformation of the boundary fault property controls the evolution of the basin's tectonic pattern from the tandem semi-mantle to the faulted anticline.  相似文献   

水资源约束下的河西走廊城市经济脆弱性时空演变及其影响因素     

张戬  陈佳  黄馨  王子侨 《中国沙漠》2019,39(1):203-211

城市经济脆弱性作为当前脆弱性研究中的重要领域，为人-地系统耦合研究提供了新的视角，并为城市可持续健康发展提供有益的决策支持和管理方法。依据城市经济脆弱性内涵，基于暴露度、敏感性、适应能力构建了城市经济脆弱性评价指标体系，运用熵权TOPSIS法评价河西走廊地区及区域内五市的城市经济脆弱性，并采用障碍度模型识别影响区域城市经济脆弱性变化的因素。结果显示：（1）2006—2015年，河西走廊地区城市经济脆弱性呈现出先曲折下降（2006—2011年）再波动上升趋势（2012—2015年）；（2）河西走廊地区的城市经济脆弱性具有明显的空间特征，经历了东西高、中部低到整体较高的演变过程；（3）阻碍河西走廊地区城市经济脆弱性降低的障碍因子由适应能力逐步转变为暴露度。针对河西走廊地区各市主要障碍因子，提出针对性优化措施。  相似文献   

Extraction of Lithium from Salt Lake Brine using N523-TBP Mixture System   总被引：1，自引：1，他引：0       下载免费PDF全文

SHI Dong  LI Li-juan  LI Jin-feng  JI Lian-min  SONG Fu-gen  PENG Xiao-wu  ZHANG Li-cheng  ZHANG Yu-ze  LI Hui-fang  SONG Xue-xue  NIE Feng  ZENG Zhong-min  LIU Zhi-qi  GUO Fan 《盐湖研究》2019,27(2):95-110

In this work,problems encountered by tri-butyl phosphate( TBP) in the industrialization of lithium extraction from salt lake brine were discussed in detail. The behavior of N,N-bi-( 2-ethylhexyl) acetamide( N523) during lithium extraction was investigated,and its disadvantages were analyzed in the view of practical application. An N523-TBP mixture extraction system was proposed to alleviate or avoid the defects that N523 and TBP met when they were used separately. The optimal composition of this mixture extraction system was determined to be 20% N523-30% TBP-50% kerosene.The effects of brine acidity,Fe/Li molarity ratio,phase ratio and chloride ion concentration on lithium extraction efficiency were discussed. The operation conditions in single-stage extraction were optimized as brine acidity = 0. 05 mol/L,Fe/Li molarity ratio = 1. 3,and phase ratio = 2. The high concentration of chloride ions in brine was beneficial for the extraction of lithium. The structure of the extracted complex was proposed as( LiFeCl_4·n N523·m TBP)·( 2-n) N523·( 2-m) TBP( m + n = 2) by chemical analysis and slope-fitting methods. The extraction thermodynamic functions were calculated preliminarily,and the results suggested that the extraction process was an exothermic( ΔH 0) and spontaneous( ΔG 0) reaction,and the degree of disorder increased( ΔS 0) during the extraction process. This work will give some guidance to the lithium industry of Qinghai in both the fundamental theory and practical application.  相似文献   

基于STIRPAT模型的内蒙古沙漠化地区环境压力分析     

樊胜岳  刘文文  周宁 《中国沙漠》2019,39(3):117-125

实现经济与生态环境的协调发展，已经成为当前治理沙漠化的巨大挑战。如何定量分析人类活动和自然条件对环境的影响，是当前环境经济学界研究的热点问题。以内蒙古自治区71个沙漠化县为研究对象，以1986—2010年为研究区间做面板空间计量实证分析。选取了人口、富裕度、技术水平、风速和降水作为环境基础指标构建STIRPAT模型，从环境压力内在驱动角度定量分析不同的自然因素和人为因素对沙漠化地区环境的综合影响。结果表明：在观测数据范围内，富裕度、技术水平、风速和降水是内蒙古自治区环境压力的主要驱动因素；富裕度每增加1%，环境压力显著增加0.096%；技术水平每变化1%，将引起环境压力相应发生0.084%的变化；风速和降水每变动1%分别使得沙漠地区环境压力显著地增加0.640%和减少0.216%。  相似文献   

我国瓯江口和珠江口凤鲚洄游模式和生境利用研究     

姜涛  刘洪波  黄洪辉  杨健 《海洋学报(英文版)》2019,38(8):35-40

Habitat use of the tapertail anchovy(Coilia mystus Linnaeus, 1758) from the Oujiang River Estuary and the Zhujiang(Pearl) River Estuary was studied by examining the environmental signatures of Sr and Ca in otoliths using electron probe microanalysis. Individuals from the Oujiang River had higher and varied Sr:Ca ratios(expressed as(Sr:Ca)×1 000, 3.83–13.0 average) in the otolith core regions, suggesting that they were born in brackish or sea waters, and that a freshwater habitat might not be necessary for egg hatching and larval growth.While, individuals from the Zhujiang River had lower Sr:Ca ratios(0.39–2.51 average) in the core regions,suggesting a freshwater origin. After hatching, anchovies from the Zhujiang River migrate downstream to the river estuary close to brackish water. Our results demonstrated varied habitat use for spawning during stages of early life history between the two populations, and suggested that such variations are promoting diversity of life history strategies of this species.  相似文献